50min - Carl Betz, Barbara Anderson, and Robert Conrad guest star alongside Jim Phelps who, with the aid of Barney's electronic wizardry, takes on the guise of a hot-shot pool hustler to break up an illegal gambling operation.
50min - Joe Collins is a nuclear scientist who is made to believe that he is a prisoner in the year 2000 and is about to be executed as part of the IMF's plans to learn where he has hidden enough plutonium to construct a dozen atomic bombs.
50min - Robert Webber guest stars as Charles Rogan, a syndicate leader with the key to the five million dollar bankroll that will finance the overthrow the government of Camagua.
50min - Robert Goulet guest stars as Joe Epic, a syndicate crime leader and key figure in an IMF plan to free a captured undercover agent.
50min - To locate a terrorist ring called Alpha Group, the IMF convinces turncoat intelligence agent Gordon Holt (played by guest star Peter Haskell) that he's been exposed to the stolen biological weapon he's been hired to deliver.
50min - William Shatner guest stars as Joe Conrad, a drug dealer who becomes the unwitting dupe of the Impossible Missions Force in their plan to capture the largest shipment of cocaine ever brought into the country.
50min - Phelps poses as a murderer to infiltrate a gang that specializes in spiriting wanted men out of the country after first brainwashing them to learn the whereabouts of their vast sums of money.
50min - Phelps poses as the head of a Hollywood movie studio as part of the IMF plan to prevent a crime syndicate's takeover of the studio.
50min - Phelps poses as a government investigator who must work through a crooked district attorney to prove that a crime syndicate boss killed his girlfriend.
50min - Phelps and Mimi take on the guises of fugitives to invade the home of Jerome Cooper, a nuclear scientist, who is threatening to destroy a major American city with a fifty-megaton hydrogen bomb.
50min - Jim Phelps is kidnapped and held for ransom until Barney, Casey, and Willy can steal an incriminating letter from a safe deposit box and turn it over to crime syndicate boss Andrew Metzger.
50min - Jim Phelps poses as a master chess champion to trap a criminal with a near genius mentality and his mysterious boss.
50min - Roddy McDowall guest stars as Leo Ostro, a brilliant crime syndicate boss who becomes the target of the IMF when he launches a mysterious one-hundred-million-dollar scheme.
50min - Kim Hunter guest stars as Hannah O'Connel a brilliant but superstitious criminal who escapes to a Caribbean country and is drawn into a voodoo ceremony by the IMF to locate a cache of stolen gold she has hidden away.
50min - Laraine Stephens guest stars as the beautiful wife of a crime syndicate boss who becomes the target of both the underworld and the Impossible Missions Force when she has her husband killed and steals his records of the syndicate's operations.
50min - Elizabeth Ashley guest stars as a beautiful IMF agent who becomes the key to determining if enemy agent Nicholai Varsi is telling the truth when he claims he's defecting to the United States.
50min - George Maharis guest stars as John Bachman, an underworld figure with access to the syndicate's top secret computerized records who is convinced by the IMF that he has found the fountain of youth.
49min - William Windom guest stars as Paul Mitchell, a boxing promoter tied to a crime syndicate who becomes a target of the IMF when one of his fighters is killed before he can talk to the police.
50min - A breathtaking motorcycle chase over the hills of San Francisco figures prominently in the IMF's plan to recover three tons of the drug commonly known as speed from Sam Hibbing's illegal drug operation.
49min - Dean Stockwell guest stars as Gunnar Malstrom, one of the leaders of Pendulum -- a secret terrorist organization -- who has a plan involving a major attack on the government that the Impossible Missions Force is assigned to uncover.
50min - Ed Nelson guest stars as Van Cleve, a brilliant thief who is convinced by the IMF that he has the power of precognition as part of its plan to recover the more than five million dollars worth of art treasures that he has stolen.
50min - Singer Barbara McNair guest stars as Jena Cole, the beautiful leader of a band of jewel thieves who falls in love with Barney who himself has infiltrated her operation to recover the stolen crown jewels of a foreign nation.
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